Inverted Ligand Field in a Pentanuclear Bow Tie Au/Fe Carbonyl Cluster

Gold chemistry has experienced in the last decades exponential attention for a wide spectrum of chemical applications, but the +3 oxidation state, traditionally assigned to gold, remains somewhat questionable. Herein, we present a detailed analysis of the electronic structure of the pentanuclear bow tie Au/Fe carbonyl cluster [Au{η²-Fe₂(CO)₈}₂]^- together with its two one-electron reversible reductions. A new interpretation of the bonding pattern is provided with the help of inverted ligand field theory. The classical view of a central gold(III) interacting with two [Fe₂(CO)₈]^2- units is replaced by Au(I), with a d¹⁰ gold configuration, with two interacting [Fe₂(CO)₈]^- fragments. A d¹⁰ configuration for the gold center in the compound [Au{η²-Fe₂(CO)₈}₂]^- is confirmed by the LUMO orbital composition, which is mainly localized on the iron carbonyl fragments rather than on a d gold orbital, as expected for a d⁸ configuration. Upon one-electron stepwise reduction, the spectroelectrochemical measurements show a progressive red shift in the carbonyl stretching, in agreement with the increased population of the LUMO centered on the iron units. Such a trend is also confirmed by the X-ray structure of the direduced compound [Au{η¹-Fe₂(CO)₈}{η²-Fe₂(CO)₆(μ-CO)₂}]^3-, featuring the cleavage of one Au-Fe bond.