A critical review of uranium contamination in groundwater: Treatment and sludge disposal

Dissolved uranium in groundwater at high concentrations is an emerging global threat to human and ecological health due to its radioactivity and chemical toxicity. Uranium can enter groundwater by geochemical reactions, natural deposition from minerals, mining, uranium ore processing, and spent fuel disposal. Although much progress has been made in uranium remediation in recent years, most published reviews on uranium treatment have focused on specific methods, particularly adsorption. This article systematically reviews the major treatment technologies, explains their mechanism and progress of uranium removal, and compares their performance under various environmental conditions. Of all treatment methods, adsorption has received much attention due to its ease of use and adaptability under various conditions. However, salinity and competition from other ions limit its application in actual field conditions. Biosorption and bioremediation are also promising methods due to their low-cost and chemical-free operation. Strong base anion exchange resins are more effective at typical groundwater pH conditions. Advanced oxidation processes like photocatalysis produce less sludge and are effective even at low uranium concentrations. Electrocoagulation shows significantly improved performance when organic ligands are added prior to treatment. The significant advantages of membrane filtration are high removal efficiency and the ability to recover uranium. While each technology has its merits and demerits, no single technology is entirely suitable under all conditions. One major area of concern with all technologies is the need to dispose of liquid and solid waste generated after treatment safely. Future research must focus on developing hybrid and state-of-the-art technologies for effective and sustainable uranium removal from groundwater. Developing holistic management strategies for uranium removal will hinge on understanding its speciation, mechanisms of fate and transport, and socio-economic conditions of the affected areas.