Versatile Synthesis of Mesoporous Crystalline TiO₂ Materials by Monomicelle Assembly

Mesoscale TiO₂ structures have realized many technological applications-ranging from catalysis and biomedicine to energy storage and conversion-because of their large mesoporosities offering desirable accessibility and mass transport. Tailoring mesoporous TiO₂ structures with novel mesoscopic and microscopic configurations is envisaged to offer ample opportunities for further applications. In this Review, we explain how to synthesize novel mesoporous TiO₂ materials and present recent examples. An emphasis is placed on a "monomicelle assembly" strategy as an emerging and powerful approach to direct the formation of mesostructured TiO₂ with precise control over its structural orientations and architectures. Furthermore, typical examples of mesoporous TiO₂ for applications in batteries and photocatalysis are highlighted. The Review ends with an outlook towards the synthesis of mesoporous TiO₂ with tailored architectures by self-assembly, which could pave the way for developing advanced energy conversion and storage devices.