Amorphous Boron Carbide on Titanium Dioxide Nanobelt Arrays for High-Efficiency Electrocatalytic NO Reduction to NH₃

Electrocatalytic NO reduction is regarded as an attractive strategy to degrade the NO contaminant into useful NH₃ , but the lack of efficient and stable electrocatalysts to facilitate such multiple proton-coupled electron-transfer processes impedes its applications. Here, we report on developing amorphous B_2.6 C supported on a TiO₂ nanoarray on a Ti plate (a-B_2.6 C@TiO₂ /Ti) as an NH₃ -producing nanocatalyst with appreciable activity and durability toward the NO electroreduction. It shows a yield of 3678.6 μg h^-1  cm^-2 and a FE of 87.6 %, superior to TiO₂ /Ti (563.5 μg h^-1  cm^-2 , 42.6 %) and a-B_2.6 C/Ti (2499.2 μg h^-1  cm^-2 , 85.6 %). An a-B_2.6 C@TiO₂ /Ti-based Zn-NO battery achieves a power density of 1.7 mW cm^-2 with an NH₃ yield of 1125 μg h^-1  cm^-2 . An in-depth understanding of catalytic mechanisms is gained by theoretical calculations.