The 3-Phase Structure of Polyesters (PBT, PET) after Isothermal and Non-Isothermal Crystallization

According to the 3-phase model, semi-crystalline thermoplastics consist of a mobile amorphous fraction (MAF), a rigid amorphous fraction (RAF), and a crystalline fraction (CF). For the two polyesters Polybutylene Terephthalate (PBT) and Polyethylene Terephthalate (PET), the composition of these phases was investigated using the largest possible variation in the isothermal and non-isothermal boundary conditions. This was performed by combining the conventional Differential Scanning Calorimetry (DSC) with the Fast Scanning Calorimetry (FSC). From the results it can be deduced that the structural composition of both polymers is characterised by a large fraction of the rigid amorphous phase. This is mainly formed either during the primary crystallization in the low temperature range or during the subsequent secondary crystallization that follows primary crystallization in the high temperature range. Depending on the thermal history, the fraction of the mobile amorphous phase of both polymers approaches a minimum, which does not appear to be undercut.