Advances of supramolecular interaction systems for improved oil recovery (IOR)

Improved oil recovery (IOR) includes enhanced oil recovery (EOR) and other technologies (i.e. fracturing, water injection optimization, etc.), have become important methods to increase the oil/gas production in petroleum industry. However, conventional flooding systems always encounter the problems of low efficiency, high cost and complicated synthetic procedures for harsh reservoirs conditions. In recent decades, the supramolecular interactions are introduced into IOR processes to simplify the synthetic procedures, alter their structures and properties with bespoke functionalities and responsiveness suitable for different conditions. Herein, we primarily review the fundamentals of several supramolecular interactions, including hydrophobic association, hydrogen bond, electrostatic interaction, host-guest recognition, metal-ligand coordination and dynamic covalent bond from intrinsic principles and extrinsic functions. Then, the descriptions of supramolecular interactions in IOR processes from categories and advances are focused on the following variables: polymer, surfactant, surfactant/polymer (SP) complex for EOR and viscoelasticity surfactant (VES) for clean hydraulic fracturing aspects. Finally, the field applications, challenges and prospects for supramolecular interactions in IOR processes are involved and systematically addressed. The development of supramolecular interactions can open the way toward adaptive and evolutive IOR technology, a further step towards the cost-effective production of petroleum industry.