Performance and mechanism of sycamore flock based biochar in removing oxytetracycline hydrochloride

In this study, sycamore flocs (SF), which caused environmental and health problems, were utilized to prepare biochar. SFB_2-900 obtained under the conditions of activation agent K₂CO₃, pyrolysis temperature 900℃ and m(K₂CO₃):m(BC) 2 had the strongest adsorption capacity (730 mg/g) for oxytetracycline hydrochloride (OTC-HCl). The pseudo-second-order kinetic model and Langmuir model described the adsorption kinetics and isotherms best. SFB_2-900 exhibited high OTC-HCl adsorption capacity in both higher ionic strength and wide pH range. The theoretical simulation indicated that the closest interaction distance between OTC-HCl and SFB_2-900 was 2.44 Å via π-π stacking configuration. Pore filling, π-π electron donor acceptor (EDA) interaction, H-bonding and electrostatic interactions were also involved in the process of OTC-HCl removal. SFB_2-900 showed great removal efficiency for OTC-HCl in different water matrices and good regeneration ability. This study solved the problems caused by SF, realized waste biomass recycling, and achieved preparing high-efficient adsorbent for antibiotic.