Deterioration of graffiti spray paints applied on granite after a decade of natural environment

Graffiti spray paints are commonly used in contemporaneous mural paintings in public spaces, contributing to the transformation of sites and urban life. These outdoor artworks are now beginning to show different deterioration forms, such as physical-mechanical alteration (loss of material and cohesion, etc.) and chromatic changes. However, the deterioration has not been formally characterized, and the influence of the paint composition and underlying substrate are not known. In this study, three non-metallic (red, blue and black) alkyd graffiti spray paints and one metallic (silver) polyethylene graffiti spray paint were applied to two granite stones with different mineralogy and texture and exposed to a natural urban-marine environment near Vigo (NW Spain) for one decade (2010-2020). Physical changes were evaluated by stereomicroscopy, colour spectrophotometry, measurements of gloss, surface roughness and static contact angle, and peeling test. Mineralogical changes were determined by x-ray diffraction and molecular changes by Fourier transform infrared spectroscopy. Moreover, micromorphological and chemical characterization of the surfaces was conducted by scanning electron microscopy. Physical-mechanical changes, such as craquelure and paint loss, depended on the texture of the granite. More specifically, paint on the granite with the finest grain size showed most intense cracking and loss of material. Chemical changes, which were not related to the granite substrate, were most intense in the red and silver paint coatings. In the red paint, loss of binder was accompanied by an intense fading of the colour (due to titanium dioxide relative enrichment), while in the silver paint coating, chemical changes occurred in both the organic binder and aluminium particles, thus darkening the colour. Fewer chemical changes were observed in the blue and black paints. Physical and chemical changes detected in these paints were not correlated.