Facile fabrication of transparent high-barrier poly(lactic acid)-based bilayer films with antioxidant/antimicrobial...

Poly(lactic acid) (PLA) has been intended as an encouraging biopolymer for packaging purposes. Nevertheless, PLA-based films suffer from low gas barrier properties, which restrict their applications. Here, we report a facile fabrication of multi-component coating via layer deposition of cinnamaldehyde (CIN)-doped chitosan/poly(vinyl alcohol)/fish gelatin (CPF) on PLA surfaces. Different PLA/CPF ratios (100:0, 77.5:22.5, 55:45, 32.5:67.5, and 0:100) were tested, whereas the PLA55:CPF45 was selected for loading of CIN. The surface and morphology analyses of the bilayers verify that CPF layers are successfully coated on the PLA surfaces. This design improved the mechanical strength and water barrier of CPF films and simultaneously enhanced the ductility of PLA films. By deposition of CIN-doped CPF layer on a PLA substrate, the oxygen permeability decreased from 28.92 to 0.238 cm³ mm/m² day bar, approximately 122 times lower than that of bare PLA. CIN loadings in the CPF layer endowed bilayer films with antioxidant/antimicrobial activity.