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Protocol for Microplastics Sampling on the Sea Surface and Sample Analysis
Published on: December 16, 2016
Ranking of potential hazards from microplastics polymers in the marine environment
Zhihao Yuan1, Rajat Nag1, Enda Cummins1
1UCD School of Biosystems and Food Engineering, University College Dublin, Belfield Dublin 4, Ireland.
Abstract:
Microplastics (MPs) have been detected globally in the marine environment. MP polymers of various kinds have different toxicity potentials when decomposed into monomers. Also, the toxicity of MPs is influenced by the particle size distribution of MPs. Based on these parameters, a semi-quantitative risk assessment model has been developed in this study to rank MP polymers of potential health concern emerging from marine exposure pathways. A screening strategy was used to categorize three probability factors and two impact factors and calculate the final risk scores. Four different scenarios were assessed to investigate the influence of risk factors on the model output. The screening strategy prioritised PUR, PVC, PAN, ABS, PMMA, SAN, TPU, UP, PET, PS, and HDPE as the top-ranking polymers of concern (descending order). The sensitivity analysis revealed parameters that influenced the final risk score were hazard score based on monomer classification (RF5 coefficient +0.60)> particle size distribution of MPs (RF4 +0.54)> annual global waste generation (RF1 +0.52)> status of degradation in the marine environment (RF3 +0.32)> mean density of polymers (RF2 +0.16). The outcome of this study can inform the scientific community and the policymakers for better management of MPs where regulation and guidelines need to be considered.
Insights
This study developed a risk model for marine microplastics (MPs), identifying polymers like PUR and PVC as high concern. The model highlights monomer toxicity and particle size as key factors for MP health risks.
Area of Science:
- Environmental Science
- Toxicology
- Polymer Science
Background:
- Microplastics (MPs) are ubiquitous in marine environments.
- The toxicity of MPs varies based on polymer type, monomer composition, and particle size.
- Understanding these factors is crucial for assessing marine ecosystem and human health risks.
Purpose of the Study:
- To develop a semi-quantitative risk assessment model for ranking microplastic polymers based on marine exposure.
- To identify specific MP polymers posing potential health concerns.
- To inform regulatory strategies for microplastic pollution management.
Main Methods:
- A screening strategy was employed, categorizing three probability and two impact factors.
- A semi-quantitative model was developed to calculate risk scores for different MP polymers.
- Sensitivity analysis was performed to determine the influence of various risk factors.
Main Results:
- The model ranked Polyurethane (PUR), Polyvinyl Chloride (PVC), and Polyacrylonitrile (PAN) as top concern polymers.
- Hazard score from monomer classification and particle size distribution significantly influenced risk scores.
- Annual global waste generation and marine degradation status also impacted the overall risk assessment.
Conclusions:
- The developed model provides a framework for prioritizing microplastic polymers of concern in marine environments.
- Findings can guide policymakers and scientists in developing targeted management and regulation strategies.
- Further research into polymer-specific degradation and monomer toxicity is warranted.
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