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Control of reactive collisions by quantum interference.

Hyungmok Son1,2, Juliana J Park1, Yu-Kun Lu1

  • 1MIT-Harvard Center for Ultracold Atoms, Research Laboratory of Electronics, Department of Physics, Massachusetts Institute of Technology, Cambridge, MA 02139, USA.

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Scientists achieved magnetic control over chemical reactions in ultracold sodium and sodium-lithium mixtures. They precisely tuned reaction rates, demonstrating unprecedented quantum control over molecular collisions using magnetic fields.

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Area of Science:

  • Atomic, Molecular, and Optical Physics
  • Quantum Chemistry
  • Ultracold Quantum Gases

Background:

  • Molecular collisions typically result in reactions or loss with near-unity probability, known as the universal rate.
  • The sodium (Na) + sodium-lithium (NaLi) system exhibits a low loss probability (~4%) in a fully spin-polarized state, deviating from universal behavior.

Purpose of the Study:

  • To investigate and demonstrate magnetic control over reactive scattering in ultracold Na + NaLi mixtures.
  • To explore the modification of molecular collision loss rates beyond the universal limit.

Main Methods:

  • Utilizing Feshbach resonances to precisely control the phase of the scattering wave function.
  • Employing magnetic fields to tune the interactions in ultracold atomic and molecular gases.

Main Results:

  • Achieved magnetic control over reactive scattering in ultracold Na + NaLi.
  • Modified the loss rate by over two orders of magnitude (factor of 100), spanning from below to above the universal limit.
  • Observed interference effects analogous to an optical Fabry-Perot resonator.

Conclusions:

  • Demonstrated quantum control of chemical reaction rates using magnetic fields.
  • Validated theoretical predictions for the full dynamic range of magnetic control in molecular collisions.
  • Opened new avenues for controlling chemical processes at the quantum level.