N-doped graphene encapsulated MoS₂nanosphere composite as a high-performance anode for lithium-ion batteries

MoS₂is widely used in lithium-ion batteries (LIBs) due to its high capacity (670 mAh g^-1) and unique two-dimensional structure. However, the further application was limited of MoS₂as anode materials suffer from its volume expansion and low conductivity. In this work, N-doped graphene encapsulated MoS₂nanosphere composite (MoS₂@NG) were prepared and its unique sandwich structure containing abundant mesopores and defects can efficiently enhance reaction kinetics. The MoS₂@NG electrode shows a reversible capacity of 975.9 mAh g^-1at 0.1 A g^-1after 100 cycles, and a reversible capacity of 325.2 mAh g^-1is still maintained after 300 cycles at 5 A g^-1. In addition, the MoS₂@NG electrode exhibites an excellent rate performance benefiting from the electrochemical properties dominated by capacitive behavior. This suggests that MoS₂@NG composite can be used as potential anode materials for LIBs.