Carbon Dioxide Conversion Synergistically Activated by Dielectric Barrier Discharge Plasma and the CsPbBr₃@TiO₂...

Carbon dioxide utilization activated by the integration of plasma and photocatalyst is a promising approach to achieve the mitigation of the greenhouse effect. In this paper, for the first time, the dielectric barrier discharge (DBD) plasma and halide perovskite photocatalysts were synergistically used to facilitate the carbon dioxide conversion. After introducing the photocatalyst into the plasma reactor, the plasma discharge characteristics were improved by the photocatalyst while the active photons, electrons, and vibrationally excited molecules in plasma also enhanced the photocatalytic activity of the photocatalyst. Compared with pure CsPbBr₃ and Al₂O₃, the CsPbBr₃@TiO₂ with the best photocatalytic activity also exhibited the best performance in plasma. The carbon dioxide conversion rate of the DBD plasma filled with CsPbBr₃@TiO₂ was found to be 29.6% higher than the sum of sole plasma and photocatalysis, illustrating the achievement of the synergistic effect between the plasma and photocatalyst. This work brings up new opportunities for efficient large-scale conversion and utilization of carbon dioxide by the coupling of nonthermal plasma and photocatalysis.