Manganese Cadmium Sulfide Nanoparticles Solid Solution on Cobalt Acid Nickel Nanoflakes: A Robust Photocatalyst for...

Photocatalytic water splitting for hydrogen evolution is one of the most promising methods to mitigate environmental and energy-related issues. In this study, manganese cadmium sulfide (Mn_x Cd_1-x S) solid solution is used to construct a p-n heterostructure with NiCo₂ O₄ through a hydrothermal method. The Mn_0.25 Cd_0.75 S/NiCo₂ O₄ composites are used for photocatalytic hydrogen evolution reaction, and the optimal hydrogen rate with 40 mg of Mn_0.25 Cd_0.75 S/NiCo₂ O₄ 40 mg (MCS/NCO 40) is 61159 μmol g^-1  h^-1 , which is about 16.3 times than that of pure Mn_0.25 Cd_0.75 S. After combining with NiCo₂ O₄ , the light absorption scale, the separation efficiency of photogenerated carriers, and the reaction kinetics are enhanced. Moreover, the band offset of MCS/NCO composites is calculated by the core level alignment method, demonstrating the formation of a p-n heterostructure. The built-in electric field from the p-n heterostructure drives charge transfer and enhances separation efficiency, which results in improved photocatalytic performance.