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Updated: Sep 30, 2025

Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts
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A Mononuclear Iron(II) Spin-Crossover Molecule Decorated by Photochromic Azobenzene Group
Jiang-Zhen Qiu1, Yong You1, Ye Yu1
1College of Chemistry and Chemical Engineering, Zhongkai University of Agriculture and Engineering, Guangzhou 510225, China.
Abstract:
Aiming at constructing photoresponsive spin crossover (SCO) behavior, herein we designed a new ligand Abtz (Abtz = (E)-N-(4-((E)-phenyldiazenyl)phenyl)-1-(thiazol-4-yl)methanimine) which was decorated by a photochromic azobenzene group. Based on this photochromic ligand, a mononuclear Fe(II) SCO molecule [Fe(Abtz)3](BF4)2·(EAC)2 (1, EAC = ethyl acetate) was successfully synthesized and showed a complete one-step SCO behavior. Under continuous UV light and blue-light exposure, the cis-trans photoisomerization of both ligand Abtz and compound 1 in the liquid phase was confirmed through UV-Vis spectra. Moreover, the 1H-NMR spectra of Abtz reveal a trans-cis conversion ratio of 37%. Although the UV-Vis spectra reveal the photochromic behavior for 1 in the solution phase, the SCO behavior in the liquid state is absent according to the variable-temperature Evans method, suggesting the possible decomposition. Moreover, in the solid state, the cis-trans photoisomerization of both Abtz and 1 was not observed, due to the steric hindrance.
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