Efficient eradication of antibiotic and dye by C-dots@zeolite nanocomposites: Performance evaluation, and degraded...

Metronidazole (MET), a recalcitrant antibiotic from the nitro-imidazole family and commercially used Rhodamine B (RhB) dye, contributes a huge to water pollution, which needs to eliminate, preferably by photocatalytic degradation technique. The Cdots@zeolite (CDZ) nanocomposites with different weight ratios (1:1, 1:3, 1:5, 5:1, 1:7) were synthesized hydrothermally to degrade MET and RhB molecules. The CDZ composites were characterized by XRD, BET, EDS, and XPS technique which verifies the crystalline nature, incorporation of C-dots into zeolite frameworks with high surface area (∼187 m²/g). The morphology, d-spacing and lattice planes were analyzed by SEM images, HR-TEM and SAED analysis. The maximum degradation (∼79%) was achieved at an optimum catalyst dose of 0.2 g/L and pH 4 for MET and that of RhB was ∼90% at a catalyst dose of 0.4 g/L. The PZC (point of zero charge) value for CDZ composite was about pH 3.4, which justifies the maximum removal of MET at pH 4. The obtained rate constants 'k' were found to be 0.0081, 0.0041, and 0.0101 min^-1 in sun, UV, and visible light sources, respectively. The real industrial wastewater sample has been treated to give ∼68% of COD and ∼62% TOC removal. Moreover, the intermediates of plausible degradation pathways were identified by the m/z values obtained from GC-MS analysis.