Stabilization of crystal and interfacial structure of Ni-rich cathode material by vanadium-doping

Stable structure and interface of nickel-rich metal oxides is crucial for practical application of next generation lithium-ion batteries with high energy density. Bulk doping is the promising strategy to improve the structural and interfacial stability of the materials. Herein, we report the impact of vanadium-doping on the structure and electrochemical performance of LiNi_0.88Co_0.09Al_0.03O₂ (NCA88). Vanadium doped in high oxidation state (+5) would lead to alteration of the crystal lattice and Li⁺/Ni²⁺ cation mixing. Those are the main factors determining the cycling and rate capability of the materials. With optimization of vanadium-doping, the preservation of the integrity of the secondary particles of the materials, the enhancement of the diffusion of Li⁺ ions, and alleviation of the side reactions of the electrolyte can be efficiently achieved. As a result, NCA88 doped with vanadium of 1.5 mol % can provide superior cycling stability with capacity retention of 84.3% after 250 cycles at 2C, and rate capability with capacity retention of 65.5% at 10C, as compared to the corresponding values of 58.6% and 55% for the pristine counterpart, respectively. The results might be helpful to the selection of dopants in the design of the nickel-rich materials.