Simultaneous determination of actinides and ⁹⁰Sr in large-size soil and sediment samples

A simultaneous analytical method for sequential separation and determination of actinides and ⁹⁰Sr in large-size environmental samples has been developed. In this method, successive co-precipitation steps were firstly conducted to remove matrix elements, then sequential column separation method was applied for simultaneous separation and purification of actinides and ⁹⁰Sr/⁹⁰Y. By using vacuum box technology, the total analytical time was minimized and batch processing allowed analyzing 12 samples in four days. The activity of ⁹⁰Sr was obtained immediately by measuring its daughter radionuclide (⁹⁰Y) with triple-to-double coincidence ratio (TDCR) Cherenkov counting, while the concentrations of Pu isotopes and ²⁴¹Am could be measured by alpha spectrometry and mass spectrometric techniques. The overall recoveries of Pu, Am, Sr and Y were higher than 70% for the entire procedure, while the recovery ratios of Sr/Y were between 0.95 and 1.04 before chromatographic separation. The developed method was verified using 20 g and 50 g of environmental soil samples spiked with certified reference materials IAEA-384 or IAEA-385 and standard solution of ⁹⁰Sr/⁹⁰Y, and good agreement between the expected values and measured results has been achieved.