Electrochemical sensor based on Ti₃C₂ membrane doped with UIO-66-NH₂ for dopamine

A Ti₃C₂ membrane was prepared by doping UIO-66-NH₂ with Ti₃C₂ through hydrogen bonds. When the doping mass ratio of Ti₃C₂ and UIO-66-NH₂ was 6:1, the electrochemical performance was optimal. Characterization was done by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and electrochemical impedance spectroscopy (EIS) which exhibited hierarchical cave-like physiognomy, large specific area, outstanding electronic conductive network, and excellent film-forming property. Moreover, the Ti₃C₂ film was analyzed via atomic force microscopy (AFM), which displayed good mechanical properties and rough surface morphology. The fabricated Ti₃C₂ membrane/GCE sensor was applied to the detection of dopamine (working potential of + 0.264 V vs. Ag/AgCl) with LOD of 0.81 fM and a sensitivity of 14.72 µA fM^-1 cm^-2. It was demonstrated that the Ti₃C₂ membrane can be used to construct nonenzymatic sensors with excellent performance. The fabricated sensor has high selectivity and stability and has good practicability with recoveries of 101.2-103.5% and a relative standard deviation (RSD) of 1.2-2.4%.