K₃ZrF₄(SbF₄)(SbF₅) and K₈(ZrF₆)(Sb₂Zr₂F₂₀): Two Zirconium Fluoroantimonites with Low Dimensional Structures and Wide...

The first examples of zirconium fluoroantimonites, namely, K₃ZrF₄(SbF₄)(SbF₅) and K₈(ZrF₆)(Sb₂Zr₂F₂₀), have been successfully synthesized by facial hydrothermal reactions. K₃ZrF₄(SbF₄)(SbF₅) features a unique 1D (ZrSb₂F₁₃)^3- double-chain structure, while K₈(ZrF₆)(Sb₂Zr₂F₂₀) displays a special 0D construction composed of Zr₂Sb₂F₂₀ tetranuclear clusters and isolated ZrF₆ octahedra. The two fluorides can exhibit a broad transparency range with almost no absorption peaks from ultraviolet to near-IR. For K₈(ZrF₆)(Sb₂Zr₂F₂₀), a phase transformation was found before decomposition. The band structures, density of states, and linear-optical properties for the title compounds were also obtained.