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Updated: Sep 30, 2025

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
Boron nitride nanosheets supported highly homogeneous bimetallic AuPd alloy nanoparticles catalyst for hydrogen
Shahram Shaybanizadeh1, Alireza Najafi Chermahini1, Rafael Luque2,3
1Department of Chemistry, Isfahan University of Technology, 84154-83111 Isfahan, Iran.
Abstract:
Formic acid (FA) has been recently regarded as a safe and stable source of hydrogen (H2). Selective and efficient dehydrogenation of FA by an effective catalyst under mild conditions is still a challenge. So, different molar ratios of bimetallic Pd-Au alloy nanoparticles were effectively stabilized and uniformly distributed on boron nitride nanosheets (BNSSs) surface via the precipitation process. Obtained catalysts were employed in FA decomposition for H2production. Pd-Au@BNNS containing 3% Au and 5% Pd (Au.03Pd.05@BNNS) exhibited high activity and 100% H2selectivity for H2production from FA at 50 °C. In order to optimize the reaction conditions, various factors including, time, temperature, solvent, base type, and amount of catalyst, were examined.
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