Passive and Dynamic Phase-Change-Based Radiative Cooling in Outdoor Weather

Radiative cooling has attracted considerable attention due to its tremendous potential in exploiting the cold reservoir of deep sky. However, overcooling always occurs in the conventional static radiative coolers because they operate only in the cooling mode in both hot and cold. Therefore, a dynamic radiative cooler based on phase change materials is highly desired. Nevertheless, the practical outdoor phase-change-based dynamic radiative cooling has not yet been experimentally demonstrated. To satisfy the stringent requirement of the phase-change-based radiative cooler in outdoor weather conditions, we engineered the phase-change material (VO₂) to possess the room-temperature phase-transition capability for typical weather conditions. Second, the reconfigurable cavity consists of the lossless spacer to ensure the magnitude of thermal modulation and suppress the solar absorption simultaneously. Third, the practical selective-filtering method is devised to shield the solar irradiance while permitting the thermal emission. Our experiment demonstrates that these materials and photonic measures can work together to realize the dynamic radiative cooling in actual weather conditions, which shows a self-adaptive switch between the ON-cooling state in hot daytime and the OFF-cooling state in cold nighttime. The study pushes the radiative cooler toward multifunctionality and provides beneficial guidance for the phase-change-based intelligent thermal control.