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Updated: Sep 29, 2025

High-throughput Synthesis of Carbohydrates and Functionalization of Polyanhydride Nanoparticles
Published on: July 6, 2012
The mechanochemical synthesis of polymers
Annika Krusenbaum1, Sven Grätz1, Getinet Tamiru Tigineh2,3
1Anorganische Chemie I, Ruhr-Universität Bochum, Universitätsstraße 150, 44801 Bochum, Germany. lars.borchardt@rub.de.
Abstract:
Mechanochemistry - the utilization of mechanical forces to induce chemical reactions - is a rarely considered tool for polymer synthesis. It offers numerous advantages such as reduced solvent consumption, accessibility of novel structures, and the avoidance of problems posed by low monomer solubility and fast precipitation. Consequently, the development of new high-performance materials based on mechanochemically synthesised polymers has drawn much interest, particularly from the perspective of green chemistry. This review covers the constructive mechanochemical synthesis of polymers, starting from early examples and progressing to the current state of the art while emphasising linear and porous polymers as well as post-polymerisation modifications.
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