ZrO₂ supported perovskite activation of peroxymonosulfate for sulfamethoxazole removal from aqueous solution

In this study, A- and B-site doped perovskite La_0.5Sr_0.5Co_0.8Ni_0.2O₃ （LSCN) was prepared by sol-gel method. On this basis, ZrO₂ supported LSCN used to maintain high catalytic activity while inhibit the leaching of toxic Co ions. Compared with the non-doped LaCoO₃, the ZrO₂@La_0.5Sr_0.5Co_0.8Ni_0.2O₃ (Z@LSCN82)/PMS system could almost completely degrade SMX in 30 min. In addition, the leaching amount of Co ions was only 0.303 mg L^-1. Free radical quenching experiments and electron paramagnetic resonance experiments proved that active species SO₄^•-, •OH and ¹O₂ existed in the Z@LSCN82/PMS system, and SO₄^•- played a major role. Besides, the catalyst had high efficiency for SMX degradation in a wide pH range. In addition, co-existing anions in water such as HPO₄^- and Cl^- also showed slight inhibition of the system. It was indicated that the Z@LSCN82/PMS system had huge potential applications for practical wastewater treatment.