Related Experiment Video
Updated: Sep 29, 2025

A Dual-Functional Electroactive Filter Towards Simultaneously SbIII Oxidation and Sequestration
Published on: December 5, 2019
A post-functional Ti-based MOFs composite for selective removal of Pb (II) from water
Zhen Huang1, Chao Xiong2, Lingri Ying1
1School of Materials Science and Engineering, Sun Yat-Sen University, Guangzhou 510006, PR China.
Abstract:
Lead ions in water have notorious effects on humans and environment. It is important to design an adsorbent with high adsorption capacity and reproducibility for efficiently removing Pb (II)ions from polluted water. Here, a novel Ti-based MOFs material (BDB-MIL-125(Ti)@Fe3O4) was prepared by modifying NH2-MIL-125(Ti) with sulfhydryl and amino groups. Due to the large number of active sites, the maximum Pb (II) adsorption capacity of BDB-MIL-125(Ti)@Fe3O4 was 710.79 mg/g at 25 °C and pH = 6 within 120 min corresponding to a maximum removal rate of 95.68%. The adsorbent also has extremely high selectivity and good cycling adsorption performance. The adsorption isotherms and kinetics agree with the Langmuir and the pseudo-second-order models, indicating that the process was chemisorption. Thermodynamic studies prove that spontaneous processes enhance Pb (II) adsorption at higher temperatures. DFT and FMOs calculations were used to discuss the adsorption mechanism. The sulfhydryl groups on the surface of organic ligands have a stronger affinity for Pb (II).
Related Concept Videos
Radical Substitution: Hydrogenolysis of Alkyl Halides with Tributyltin Hydride
The bonds formed in this reaction are stronger than the bonds broken, making it energetically favorable. The reaction follows a radical chain mechanism similar to radical halogenation...
Extraction: Advanced Methods
Precipitation and Co-precipitation
Coagulation
Factors Affecting Solubility

