Co-doped Fe-MIL-100 as an adsorbent for tetracycline removal from aqueous solution

In the study, Fe-MIL-100 was modified by adding Co²⁺ in the synthesis process; Co/Fe-MIL-100 was successfully synthesized and used to adsorb tetracycline. The addition of Co²⁺ increased the thermal stability of Fe-MIL-100 without changing the crystal structure. It was found that Co/Fe-MIL-100 exhibited satisfactory performance in tetracycline removal, the tetracycline removal efficiency reached almost 100% in the initial concentration range of 10-40 mg/L, and it still reached 82.38% under the condition of 60 mg/L tetracycline. Besides, the factors of tetracycline concentration, pH and inorganic anion on removal efficiency were explored. The coexistence of inorganic anion decreased the adsorption capacity of tetracycline due to the competitive adsorption. CO₃^2- had a more obvious inhibition effect on the adsorption efficiency of tetracycline than Cl^-. The fitting correlation coefficient of Langmuir model was higher and the kinetics better fitted by pseudo-second-order, respectively. As a result of its high removal efficiency and excellent recycling performance, it has great potential in application fields such as removing tetracycline from wastewater.