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Updated: Sep 29, 2025
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Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of ChalcogenidoplumbatesII or IV
Published on: December 29, 2016
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Structural Diversity of Rare-Earth Oxychalcogenides
Melissa Orr1, Glen R Hebberd2, Emma E McCabe2
1Department of Chemistry and Biochemistry, University of Texas at Arlington, Arlington, Texas 76019, United States.
ACS Omega
|March 21, 2022
Summary
Solid-state chemists are exploring mixed-anion compounds, like rare-earth oxychalcogenides, for advanced applications. This review covers their structural diversity and synthetic methods, from 2D layers to 3D networks.
Area of Science:
- Solid-state chemistry
- Materials science
- Inorganic chemistry
Background:
- Mixed-anion systems offer unique properties for energy conversion, electronics, and catalysis.
- Rare-earth containing materials are crucial for modern technologies.
- Oxychalcogenides represent a promising class of mixed-anion compounds.
Purpose of the Study:
- To review recent advances in rare-earth oxychalcogenides.
- To discuss the structural diversity of ternary and quaternary rare-earth oxychalcogenides.
- To highlight the progression towards 3D networks and novel synthetic approaches.
Main Methods:
- Review of existing literature on rare-earth oxychalcogenides.
- Analysis of structural characteristics of ternary and quaternary compounds.
- Discussion of synthetic strategies for layered and network structures.
Main Results:
- Ternary rare-earth oxychalcogenides exhibit layered structures showcasing oxide and chalcogenide anion behavior.
- Quaternary compounds demonstrate combined anionic and cationic design, leading to structural diversity.
- Advancements include the transition from 2D layered materials to 3D networks.
Conclusions:
- Rare-earth oxychalcogenides are a key area of mixed-anion materials research.
- Structural complexity and synthetic methods are advancing the field.
- These materials hold significant potential for future technological applications.
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