Significant contribution of lightning NO_x to summertime surface O₃ on the Tibetan Plateau

Lightning generates nitrogen oxides (NO_x) in the troposphere, an important precursor of tropospheric ozone (O₃). The Tibetan Plateau (TP) is considered to be a global atmospheric background location with limited anthropogenic influences. However, the observed summertime surface O₃ concentration on the TP is 25% higher than that in highly polluted regions (e.g., southern China). Previous studies have suggested that lightning-produced NO_x (LNO_x) can affect the concentration of surface O₃. We used the Weather Research and Forecasting coupled with chemistry (WRF-Chem) model combined with satellite, ground-based, and airborne observations to evaluate the contribution of LNO_x to the surface O₃ budget on the TP. Our results showed that LNO_x contributed approximately 15% of the surface NO_x emission on the TP in summer. Accordingly, the contribution of LNO_x to the summertime surface daily maximum 8-h average (MDA8) O₃ on the TP was 9.3 ± 7.1 ppb, which was 17.5% ± 14.5% of the total concentration of the surface MDA8 O₃. In addition, our study found that the number of moles of NO produced per lightning flash (LNO_x production efficiency) significantly affected the surface concentration of NO_x, OH, and MDA8 O₃. Increasing the LNO_x production efficiency (PE) from 0 to 330 mol NO flash^-1 increased the concentration of MDA8 O₃ by up to 20% on the TP. Our study revealed that lightning significantly affects the atmospheric chemical processes involving O₃ on the TP.