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Related Experiment Videos

Cheng Peng1, Chongwen Li2, Mingzhe Zhu1

  • 1College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042, P. R. China.

Angewandte Chemie (International Ed. in English)
|March 25, 2022
PubMed
Summary

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Researchers used 1-bromo-4-(methylsulfinyl)benzene (BBMS) to improve Sn-Pb perovskite films. This treatment enhanced device efficiency to over 22% and boosted long-term stability.

Area of Science:

  • Materials Science
  • Chemistry
  • Physics

Background:

  • Perovskite solar cells offer promising photovoltaic properties.
  • Energy disorder in Sn-Pb alloyed perovskite films limits device performance and stability.
  • Developing effective strategies to mitigate energy disorder is crucial for advancing perovskite technology.

Purpose of the Study:

  • To investigate the use of an organic small molecule, 1-bromo-4-(methylsulfinyl)benzene (BBMS), for reducing energy disorder in Sn-Pb alloyed perovskite films.
  • To evaluate the impact of BBMS treatment on the efficiency and stability of perovskite devices.

Main Methods:

  • Treatment of Sn-Pb alloyed perovskite films with 1-bromo-4-(methylsulfinyl)benzene (BBMS).
  • Analysis of interactions, including hydrogen bonding and coordination bonding, between BBMS and the perovskite film.
Keywords:
Energy DisorderPerovskiteSn−Pb AlloyStabilityUrbach Energy

Related Experiment Videos

  • Fabrication and characterization of BBMS-treated perovskite devices to assess performance metrics.
  • Main Results:

    • BBMS effectively reduced energy disorder in the Sn-Pb alloyed perovskite film.
    • The BBMS-treated device achieved a power conversion efficiency exceeding 22%.
    • The treated devices demonstrated significantly improved long-term operational stability.

    Conclusions:

    • 1-bromo-4-(methylsulfinyl)benzene is a viable additive for enhancing perovskite film quality.
    • BBMS treatment improves both the efficiency and stability of Sn-Pb alloyed perovskite solar cells.
    • This approach offers a promising pathway for developing high-performance and durable perovskite photovoltaic devices.