Durably Self-Sustained Droplet on a Fully Miscible Liquid Film

Droplets impacting onto a solid or liquid surface inducing wetting, floatation, splash, coalescence, etc. is ubiquitous in nature and industrial processes. Here, we report that liquid droplets exhibit spherical caps upon contact with a fully miscible liquid film of lower surface tension, despite the spontaneous mixing of the two liquids. Such a spherical cap on a continuous liquid surface sustains a long lifespan up to minutes before ultimately merging into the film. Benefiting from large viscous forces in a thin film as a result of spatial confinement, the surface flow is substantially suppressed. Therefore, the surface tension gradient responsible for this phenomenon is maintained because the normal diffusion of film liquid into the droplet can timely dilute film liquid supplied by uphill Marangoni flow at the droplet surface. The present finding removes the conventional cognition that droplet coalescence is prompt on fully miscible continuous liquid surfaces, thus benefiting design of new types of microfluidic devices.