Large contribution of non-priority PAHs in atmospheric fine particles: Insights from time-resolved measurement and...

Polycyclic aromatic hydrocarbons (PAHs), detrimental to human health, are key components contributing to the carcinogenicity of fine particles. The 16 priority PAHs listed by the United States Environment Protection Agency have been studied extensively. However, other than them, there is a large diversity of PAH species, whose atmospheric concentrations, risks, and variations remain elusive. Here, we carried out a time-resolved nontarget measurement in atmospheric PM_2.5 using an improved comprehensive two-dimensional gas chromatography mass spectrometry. The measurement conducted during a 5-day pollution episode at an urban site of Beijing with a time resolution of 2 h. The nontarget analysis of time-resolved chromatographic data was performed for screening PAHs. A total number of 85 PAHs were identified and quantified. We found that other than 16 EPA PAHs, other screened PAHs contributed 43.3% of the total PAH mass concentration and 40.8% poential health risks. Dynamic variations of mass concentrations and their potential health risks of the screened PAHs were captured during a short-term heavy pollution episode, during which the instantaneous PAHs concentrations were much higher than their average concentrations. This study shows the potential for application of nontarget analysis for online comprehensive two-dimensional gas chromatography mass spectrometry and highlights the importance of time-resolved measurement of PAHs in PM_2.5 and attention on extended PAHs species other than 16 EPA PAHs.