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Updated: Sep 28, 2025

Synthesis of Monodisperse Cylindrical Nanoparticles via Crystallization-driven Self-assembly of Biodegradable Block Copolymers
Published on: June 20, 2019
Self-Assembly of Copolymers Containing Crystallizable Blocks: Strategies and Applications
Boyang Shi1, Ding Shen1, Wei Li2
1State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, 200433, P. R. China.
Abstract:
The self-assembly of copolymers containing crystallizable blocks in solution has received increasing attention in the past few years. Various strategies including crystallization-driven self-assembly (CDSA) and polymerization-induced CDSA (PI-CDSA) have been widely developed. Abundant self-assembly morphologies are captured and advanced applications have been attempted. In this review, the synthetic strategies including the mechanisms and characteristics are highlighted and a survey on the advanced applications of crystalline nano-assemblies is collected. This review is hoped to depict a comprehensive outline for self-assembly of copolymers containing crystallizable blocks in recent years and to prompt the development of the self-assembly technology in interdisciplinary fields.
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