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Updated: Sep 28, 2025
Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
Published on: April 9, 2018
Two-dimensional coordination polymers with high proton conductivity and ultrafast highly efficient molecular sieving
Lian Zhou1,2, Mingming Ruan3, Wei Meng1
1State Key Laboratory of Plateau Ecology and Agriculture, New Energy Photovoltaic Industry Research Center, Qinghai University, Xining 810016, P. R. China. Zhangjun@ahjzu.edu.cn.
Abstract:
A family of unique 2D-layered Cu-based coordination polymers (abbreviated as HNNU-1α, 1β and 1γ) with different halide anions were successfully constructed using a zwitterion pyridiniumolate as the structural inductive agent (SIA). More importantly, we found that the laminates of HNNU-1α exhibit ultrafast highly-efficient molecular sieving in a water system, and HNNU-1α to 1γ display a good proton conductivity of ca. 2.2 × 10-2, 4.9 × 10-5, and 3.0 × 10-4 S cm-1 at 90 °C and 98% relative humidity (RH), respectively.
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