MoP Quantum Dot-Modified N,P-Carbon Nanotubes as a Multifunctional Separator Coating for High-Performance...

Lithium-sulfur batteries (LSBs) have the advantages of high energy density and low cost and are considered promising next-generation energy storage systems, but the shuttle effect and slow sulfur redox kinetics severely limit their practical applications. Herein, MoP quantum dot-modified N,P-doped hollow PPy substrates are adopted as separator modification coatings for LSBs. The MoP quantum dots exhibit excellent chemisorption and catalytic conversion capabilities for polysulfides, while the N,P-doped PPy substrates can provide flexible channels for Li⁺/electron transport and act as a physical barrier to suppress the shuttle effect. As a result, LSBs assembled with modified separators exhibit excellent rate capability (739 mAh/g at 3 C) and cycle performance (600 mAh/g at 1 C after 600 cycles, 0.052% decay per cycle). Moreover, even under a high sulfur loading of 3.68 mg/cm², areal capacities of 3.58 and 2.92 mAh/cm² for the 1st cycle and 110th cycle are achieved. In addition, according to density functional theory calculations, MoP quantum dots have large adsorption energy for S₈ and Li₂S, which further confirms the possibility of lowering the initial nucleation energy barrier of Li₂S and helps to improve the kinetics of the subsequent Li₂S reaction. This study proposes a novel method for using transition-metal phosphides as catalysts in high-performance LSBs.