A comprehensive review on persulfate activation treatment of wastewater

With increasingly serious environmental pollution and the production of various wastewater, water pollutants have posed a serious threat to human health and the ecological environment. The advanced oxidation process (AOP), represented by the persulfate (PS) oxidation process, has attracted increasing attention because of its economic, practical, safety and stability characteristics, opening up new ideas in the fields of wastewater treatment and environmental protection. However, PS does not easily react with organic pollutants and usually needs to be activated to produce oxidizing active substances such as sulfate radicals (SO₄^-) and hydroxyl radicals (OH) to degrade them. This paper summarizes the research progress of PS activation methods in the field of wastewater treatment, such as physical activation (e.g., thermal, ultrasonic, hydrodynamic cavitation, electromagnetic radiation activation and discharge plasma), chemical activation (e.g., alkaline, electrochemistry and catalyst) and the combination of the different methods, putting forward the advantages, disadvantages and influencing factors of various activation methods, discussing the possible activation mechanisms, and pointing out future development directions.