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Updated: Sep 28, 2025

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
Published on: August 12, 2013
Engineering a ternary one-dimensional Fe2P@SnP0.94@MoS2 mesostructure through magnetic-field-induced self-assembly as
Jinyun Liu1, Ting Zhou1, Tianli Han1
1Key Laboratory of Functional Molecular Solids (Ministry of Education), Anhui Provincial Engineering Laboratory for New-Energy Vehicle Battery Energy-Storage Materials, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241002, P. R. China. jyliu@iim.ac.cn.
Abstract:
Engineering energy-storage materials possessing high-speed electronic and ionic transport properties for secondary batteries is significant. Here, we develop a ternary one-dimensional mesostructured anode composed of MoS2 nanosheets grown in situ on SnP0.94 nanotubes infilled with Fe2P nanospheres, which is prepared by magnetic-field-induced self-assembly. The mesostructure provides fast transport pathways for electrons, as verified through a galvanostatic intermittent titration technique; and the voids effectively alleviate the volume change, enabling long-term cycling stability. The Fe2P@SnP0.94@MoS2 anode displays a high capacity of 797.5 mA h g-1 after cycling 800 times at 2 A g-1, a coulombic efficiency of 99.4%, and stable rate-performance after three rounds of cycling. Furthermore, the anode shows high capacities at different temperatures, indicating that the composite presented here has a promising potential for use in real conditions.

