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Updated: Sep 28, 2025

Using Cyclic Voltammetry, UV-Vis-NIR, and EPR Spectroelectrochemistry to Analyze Organic Compounds
Published on: October 18, 2018
Experimental Voltammetry Analyzed Using Artificial Intelligence: Thermodynamics and Kinetics of the Dissociation of
Haotian Chen1, Danlei Li1, Enno Kätelhön2
1Department of Chemistry, Physical and Theoretical Chemistry Laboratory, Oxford University, South Parks Road, Oxford OX1 3QZ, Great Britain.
Abstract:
Artificial intelligence (AI) is used to quantitatively analyze the voltammetry of the reduction of acetic acid in aqueous solution generating thermodynamic and kinetic data. Specifically, the variation of the steady-state current for the reduction of protons at a platinum microelectrode as a function of the bulk concentration of acetic acid is recorded and analyzed giving data in close agreement with independent measurements, provided the AI is trained with accurate and precise knowledge of diffusion coefficients of acetic acid, acetate ions, and H+.
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