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Magnetic MnFe2O4/ZnFe-LDH for Enhanced Phosphate and Cr (VI) Removal from Water
Congxin Huang1, Chaochun Tang2, Qingqing Wu1
1School of Civil Engineering and Architecture, East China Jiao Tong University, Jiangxi, 330013, China.
Abstract:
Due to the layered structure and recycling characteristics, magnetic MnFe2O4/ZnFe-LDH was prepared by co-precipitation. In this study, we intensively explored MnFe2O4/ZnFe-LDH for water purification compared with the ZnFe-LDH. The morphological and structural characteristics of the obtained products were systematically characterized. MnFe2O4/ZnFe-LDH exhibits the maximum adsorption capacity of 94.52 mg/g for phosphate and 49.03 mg/g for Cr (VI), respectively, which is superior to that of the ZnFe-LDH, indicating that the magnetic MnFe2O4 effectively enhanced adsorption performance. Meanwhile, the mechanism of adsorption of phosphate and Cr (VI) was briefly studied, where the metal center ion in MnFe2O4/ZnFe-LDH and between layers of SO42- serves as capture sites for phosphate and Cr (VI) removal. Furthermore, the MnFe2O4/ZnFe-LDH can be used for magnetic recycled and still maintained excellent removal efficiency (70%) for phosphate and Cr (VI) after five adsorption-desorption cycles. This work could open a new vista of designing magnetic novel adsorbents in environmental remediation.
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