Glass Fiber-Epoxy Composites with Boron Nitride Nanotubes for Enhancing Interlaminar Properties in Structures

Hybrid composite materials are a class of materials where more than one type of reinforcement is integrated into a matrix to achieve superior properties. This typically involves nanoparticle fillers employed within traditional advanced composites with fiber reinforcements such as carbon or glass. The current study builds on previous investigations of boron nitride nanotube (BNNT) hybrid composites, specifically glass fiber (GF)-epoxy/BNNT composite laminates. GF is an effective and affordable primary reinforcement fiber in many applications, and boron nitride nanotubes (BNNTs) exhibit impressive mechanical properties comparable to carbon nanotubes (CNTs) with distinct functional properties, such as electrical insulation, which is desirable in manufacturing insulating composites when combined with GF. GF-epoxy/BNNT composite laminates, incorporating BNNT materials with different loadings (1 and 2 wt %) and purity, were manufactured using a hand layup technique and prepared for three-point bending, modified Charpy, dynamic mechanical analysis (DMA), and fracture toughness (mode I and mode II) measurements. A comprehensive microscopy study was also performed using scanning electron microscopy (SEM) showing prominent failure mechanism, nanotube dispersion, and their mode of reinforcement in different loading scenarios. Enhanced properties, including a 43% increase in mode II fracture toughness, were observed in hybrid composites with 1 wt % BNNT compared to the GF composites with neat epoxy, and the reinforcement mechanisms were discussed.