Development of a Lightweight LTO/Cu Electrode as a Flexible Anode via Etching Process for Lithium-Ion Batteries

In recent years, flexible energy storage devices have attracted the growing demand for flexible electronic systems. Therefore, research on reliable electrodes with high mechanical flexibility and good electronic and lithium-ion conductivity has become critical. Carbon-coated Li₄Ti₅O₁₂ (LTO) nanostructures find essential applications in high-performance lithium-ion batteries (LiBs). Nevertheless, the conventional copper current collector with a thickness of several micrometers accounts for a large proportion of the LiB, making the low-energy density LiB with much less flexibility. Here, hundred nm-thick (LTO/Cu) copper foil-LTO nanostructures are fabricated using a scalable and straightforward process which can be assembled into a film into a flexible, lightweight electrode by etching a conventional copper foil to form an ultra-thin copper layer for LIBs (<1 μm). This process provides essential flexibility to the as-prepared electrode and provides template support for simple fabrication. The LiB cell using the novel LTO/Cu as the anode exhibits an energy capacity of 123 mA h/g during 40 charge-discharge cycles at a 0.1C rate. Besides, the coulombic efficiency of the LiB using LTO/Cu remains over 99% after 40 cycles. These results show the uses of this novel anode and its potential in high-density and flexible commercial lithium-ion batteries.