Highly Synergistic Sensor of Graphene Electrode Functionalized with Rutile TiO₂ Microstructures to Detect...

Electrochemical processes are an effective method for detecting dangerous food ingredients. The synergistic between the reduction-oxidation (redox) processes inspired several papers and spurred research towards studying the new materials that can further adapt to optimize the rapid detection of chemical compounds. In this study, we report the eco-synthesis using graphene/TiO₂ rutile (G/TiO₂) electrode microstructures easily prepared through the physical method by mixing graphene and TiO₂ powder and its application for sensing L-tryptophan (Trp) compound. The material characterization results show that the graphene surface is smoother than the G/TiO₂ material. Graphene has been detected using X-ray diffraction (XRD) at a value of 2 thetas 26.39° and TiO₂ forms rutile crystals (110). The FTIR spectrum exhibits the functional groups from graphene of -OH, C-H, C=C, C-O, and TiO₂ identified with Ti-O bonds. The electrochemical test against G/TiO₂ electrode microstructures for Trp compound shows that 0.5 g TiO₂ rutile was the best composition functionalized with graphene material under 0.1M K₃[Fe(CN)₆] + 0.1M NaNO₃ electrolyte with a scan rate of 0.1 V/s. Determination of the detection limit was obtained at 0.005 mg/L with a HorRat value of 1.05%. The stability test was carried out for 25 days, and the addition of Pb(NO₃)₂ as an interference compound had a significant effect on the decrease in electrode performance.