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Updated: Sep 27, 2025

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Spin-orbit coupling and the fine optical structure of chiral helical polymers
Mengzhao Du1, Xuan Liu1, Shijie Xie1
1School of Physics, State Key Laboratory of Crystal Materials, Shandong University, Ji'nan 250100, China. xsj@sdu.edu.cn.
Abstract:
With the discovery of the chiral-induced spin selectivity (CISS) effect, it has been recognized that spin and structural spin-orbit coupling (SOC) play important roles in the electro-optical properties of chiral materials. We redefine the spin-dependent current and magnetic moment operators to include chiral-induced SOC in a helical polymer and deduce optical absorption and circular dichroism (CD) formulae. The fine structure in the optical spectra is calculated for a helical polymer described with the tight-binding model. The effects of both the electron orbit and spin on the optical absorption and CD are discussed. Our investigations demonstrate that the synergy between the electron orbit and spin will contribute to higher-sensitivity circularly polarized light (CPL) detection.
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