Hierarchical NiCo₂S₄/ZnIn₂S₄ heterostructured prisms: High-efficient photocatalysts for hydrogen production under...

Exploring low-cost co-catalyst to ameliorate the photocatalytic activity of semiconductors sets a clear direction for solving energy crisis and achieving efficient solar-chemical energy conversion. In this work, a unique hierarchical hollow heterojunction was constructed by in-situ growing ZnIn₂S₄ nanosheets on the porous NiCo₂S₄ hollow prisms through a low temperature solvothermal method, in which NiCo₂S₄ with semi-metal property acted as non-noble metal co-catalyst. NiCo₂S₄ co-catalyst was innovatively encapsulated in ZnIn₂S₄, which not only relieved the light shielding effect caused by the large loading amount of co-catalyst, but also supplied abundant active sites for H₂ evolution. The hierarchical hollow heterostructure of NiCo₂S₄/ZnIn₂S₄ provided a highly efficient channel for charge transfer. Combining these advantages, NiCo₂S₄/ZnIn₂S₄ composite demonstrated excellent photocatalytic activity. In the absence of sacrificial agent, the NiCo₂S₄/ZnIn₂S₄ photocatalyst achieved a remarkable improved H₂ yield of 0.77 mmol g^-1h^-1 under visible light irradiation (λ > 400 nm), which is 6.6 times greater than that of ZnIn₂S₄. Besides, NiCo₂S₄ even exhibited better performance on the H₂ evolution improvement of ZnIn₂S₄ than precious metal Pt. This work will offer novel insights into the reasonable design of non-noble metal photocatalysts with respectable activity for water splitting.