Core-shell structured Z-scheme Ag₂S/AgIO₃ composites for photocatalytic organic pollutants degradation

Constructing direct Z-scheme system is a promising strategy to boost the photocatalytic performance for pollution waters restoration, but it is of great challenge because of the requirement of appropriately staggered energy band alignment and intimate interfacial interaction between semiconductors. Herein, a class of core-shell structured Ag₂S-AgIO₃ Z-scheme heterostructure photocatalysts are designed and developed. Ag₂S is generated by the in-situ ion exchange reaction and anchored on the surface of AgIO₃, so the intimate interface between AgIO₃ and Ag₂S is realized. Integration of AgIO₃ and Ag₂S extends the ultraviolet absorption of AgIO₃ to Vis-NIR region, and also promote the charge separation and migration efficiency, contributing to the enhanced photocatalysis activity for composite catalysts. The optimal Ag₂S-AgIO₄-4 catalyst exhibits a MO photo-degradation rate constant of 0.298 h^-1, which reaches 5.77 and 11.4-folds higher than that of AgIO₃ (0.044 h^-1) and Ag₂S (0.024 h^-1). The as-obtained composite catalyst exhibits universally photocatalytic activity in disintegrating diverse industrial pollutants and pharmaceuticals. Particularly, driven by natural sunlight, the Ag₂S-AgIO₄-4 can effectively decompose MO. A plausible Z-scheme photocatalytic mechanism and reaction pathways of MO degradation over composite catalyst are systemically investigated and proposed.