Spatial characteristics of fine particulate matter in subway stations: Source apportionment and health risks

Air in subway stations is typically more polluted than ambient air, and particulate matter concentrations and compositions can vary greatly by location, even within a subway station. However, it is not known how the sources of particulate matter vary between different areas within subway stations, and source-specific health risks in subway stations are unclear. We analyzed the spatial characteristics of particulate matter by source and calculated source-specific health risks on subway platforms and concourses and in station offices by integrating source apportionment with health risk assessments. A total of 182 samples were collected in three areas in six subway stations in Nanjing, China. Enrichment factors and the positive matrix factorization receptor model were used to identify major sources. The carcinogenic and non-carcinogenic health risks to subway workers and passengers were evaluated to determine control priorities. Seven sources of particulate matter were identified in each area, with a total of four subway sources and six outdoor sources over all the areas. The source contributions to total element mass differed significantly from the source contributions to human health risks. Overall, subway sources contributed 48% of total element mass in the station office and 75% and 60% on the concourse and platform, respectively. Subway-derived sources accounted for 54%, 81%, and 71% of non-carcinogenic health risks on station platforms, concourses, and office areas, respectively. The corresponding values for carcinogenic risks were 51%, 86%, and 86%. Among the elements, cobalt had the largest contributions to carcinogenic and non-carcinogenic risks, followed by manganese for non-carcinogenic risks and hexavalent chromium for carcinogenic risks. Reducing emissions from subway sources could effectively protect the health of subway workers and passengers.