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Search for New Anode Materials for High Performance Li-Ion Batteries
Kingshuk Roy1, Abhik Banerjee1, Satishchandra Ogale1,2
1Research Institute for Sustainable Energy, Centers for Research and Education in Science and Technology (TCG-CREST), Salt Lake, Kolkata 700091, India.
ACS Applied Materials & Interfaces
|April 12, 2022
Summary
Researchers are exploring new anode materials for lithium-ion batteries to overcome graphite limitations. This review covers conversion, insertion, alloying, and framework systems for improved energy storage and cost reduction.
Area of Science:
- Materials Science
- Electrochemistry
- Energy Storage
Background:
- Lithium-ion batteries offer superior energy density and stability but face limitations with graphite anodes.
- Increasing demands for higher energy and power density necessitate exploring alternative anode materials.
- Cost reduction is crucial, driving research into earth-abundant materials for battery electrodes.
Purpose of the Study:
- To review recent advancements in alternative anode materials for lithium-ion batteries.
- To provide perspective on ongoing research, including the authors' work.
- To discuss the potential impact of novel anode materials on energy storage.
Main Methods:
- Review of conversion anode systems (oxides, sulfides).
- Analysis of insertion/alloying systems (transition metal carbides).
- Exploration of molecularly engineered open framework systems (MOFs, COFs, OIHPs).
Main Results:
- Identified diverse classes of alternative anode materials beyond graphite.
- Highlighted progress in conversion, insertion/alloying, and framework-based anodes.
- Detailed the potential of these materials to enhance Li-ion battery performance.
Conclusions:
- Alternative anode materials are essential for meeting future lithium-ion battery demands.
- Novel materials like MOFs, COFs, and OIHPs show significant promise.
- Further research is critical for developing cost-effective, high-performance Li-ion battery anodes.

