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Updated: Sep 27, 2025
Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
H2 and carbon-heteroatom bond activation mediated by polarized heterobimetallic complexes
R Malcolm Charles1, Timothy P Brewster1
1Department of Chemistry, The University of Memphis, 3744 Walker Ave., Smith Chemistry Building, Memphis, TN 38152, United States.
Abstract:
The field of heterobimetallic chemistry has rapidly expanded over the last decade. In addition to their interesting structural features, heterobimetallic structures have been found to facilitate a range of stoichiometric bond activations and catalytic processes. The accompanying review summarizes advances in this area since January of 2010. The review encompasses well-characterized heterobimetallic complexes, with a particular focus on mechanistic details surrounding their reactivity applications.
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