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![[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Organic-photoredox-catalyzed three-component sulfonylative pyridylation of styrenes
Fang Wang1, Jian Qin1, Shengqing Zhu1
1State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-Dimension Materials, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University Shanghai 201620 China Lingling.chu1@dhu.edu.cn zhusq@dhu.edu.cn.
Abstract:
An efficient, metal-free protocol for the three-component sulfonylative pyridylation of styrenes via organic-photoredox catalysis is described. This metal-free process enables the direct and selective installation of sulfonyl and heteroaryl motifs and tolerates a wide array of functional groups as well as complex molecular scaffolds, that could complement previous methods and would be of interest in pharmaceutical research.
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