Scale-up experiments of SO₂ removal and the promoting behavior of NO in moving beds at medium temperatures

The dry flue gas desulfurization (FGD) method was studied, which is a part of the integrated removal of multi-pollutants at medium temperatures. Although dry flue gas treatment is a simple and effective method, it is still a highly empirical-led application technology. A superior desulfurization adsorbent, fine powder of NaHCO₃ (hereinafter called fine NaHCO₃), was selected by scale-up experiments. A deep understanding of the reaction process and mechanism is then explored, which helps the further optimization of dry desulfurization. Based on the multi-factor experiments for NaHCO₃, the effect mechanism of NO on desulfurization using NaHCO₃ is also proposed. The conversion of SO₃ ^2- → SO₄ ^2- is promoted by the existence of NO. Therefore, a slight decline can be found. According to the influences of the SO₂ concentration and the residence time, it is concluded that the diffusion of SO₂ into the channel of NaHCO₃ is the rate-limiting step. Impressively, the reaction process of reactants was clearly studied by in situ FTIR spectroscopy to determine the whole process. Moreover, the recycling of NaHCO₃ is the main direction for reducing adsorbent consumption in the next step. The predictable insights are beneficial for profoundly understanding the gas composition synergetic interaction for the SO₂ removal by the dry treatment using NaHCO₃.