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CaCO3 blowing agent mixing method for biomass composites improved buffer packaging performance
Kai-Qiang Sun1,2, Fang-Yi Li1,2, Jian-Yong Li1,2
1Key Laboratory of High Efficiency and Clean Mechanical Manufacture, Ministry of Education, School of Mechanical Engineering, Shandong University Jinan 250061 China lifangyi@sdu.edu.cn.
RSC Advances
|April 15, 2022
Summary
Calcium carbonate (CaCO3) as a nucleating agent creates uniform, biodegradable composite foams for packaging. Optimal performance was achieved at 5 wt% CaCO3, enhancing cushioning and thermal stability.
Area of Science:
- Materials Science
- Polymer Science
- Sustainable Materials
Background:
- Petroleum-based packaging materials pose environmental concerns.
- Development of biodegradable alternatives is crucial for sustainable packaging solutions.
- Achieving uniform foam structures in biodegradable composites presents a challenge.
Purpose of the Study:
- To develop biodegradable composites with an open-cell structure as replacements for petroleum-based packaging.
- To investigate the effect of calcium carbonate (CaCO3) as a nucleating agent on composite foam properties.
- To optimize the CaCO3 content for enhanced cushioning and material stability.
Main Methods:
- Preparation of biodegradable composites using CaCO3 as a nucleating agent.
- Characterization of composite cell structure, density, and cushioning performance.
- Evaluation of thermal stability and moisture absorption properties.
- X-ray diffraction (XRD) analysis to determine changes in material crystallinity.
Main Results:
- Addition of 5 wt% CaCO3 resulted in uniform and dense composite cells with improved cushioning.
- Higher CaCO3 content led to decreased cell density and cushioning properties.
- CaCO3 enhanced thermal stability and water barrier properties, reducing moisture absorption by 15%.
- XRD analysis confirmed that CaCO3 disrupted starch crystallinity, promoting homogeneous slurry formation and uniform foaming.
Conclusions:
- CaCO3 effectively acts as a nucleating agent to produce uniform biodegradable composite foams.
- Optimizing CaCO3 content is critical for achieving desired cushioning and material properties.
- These biodegradable composites offer a sustainable alternative to petroleum-based packaging with improved performance characteristics.

